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Literature summary for 1.11.2.1 extracted from

  • Ullrich, R.; Poraj-Kobielska, M.; Scholze, S.; Halbout, C.; Sandvoss, M.; Pecyna, M.J.; Scheibner, K.; Hofrichter, M.
    Side chain removal from corticosteroids by unspecific peroxygenase (2018), J. Inorg. Biochem., 183, 84-93 .
    View publication on PubMed
Search for more literature for 1.11.2.1

Metals/Ions

Metals/Ions Comment Organism Structure
Mg2+ contains Mg2+ Marasmius rotula

Molecular Weight [Da]

Molecular Weight [Da] Molecular Weight Maximum [Da] Comment Organism
58
-
 gel filtration Marasmius rotula
62
-
 gel filtration Marasmius wettsteinii

Organism

Organism UniProt Comment Textmining
Cyclocybe aegerita B9W4V6
-
-
Marasmius rotula A0A023H437
-
-
Marasmius wettsteinii
-
-
-
Marasmius wettsteinii DSM 106021
-
-
-

Purification (Commentary)

Purification (Comment) Organism
-
 Marasmius wettsteinii

Specific Activity [micromol/min/mg]

Specific Activity Minimum [µmol/min/mg] Specific Activity Maximum [µmol/min/mg] Comment Organism
26
-
 with veratryl alcohol as substrate, at pH 5.5 and 23°C Marasmius rotula
99.6
-
 with veratryl alcohol as substrate, at pH 7.0 and 23°C Cyclocybe aegerita

Substrates and Products (Substrate)

Substrates Comment Substrates Organism Products Comment (Products) Rev. Reac.
11-deoxycortisol + H2O2 Reichstein's substance S Marasmius rotula ? + H2O
-
 ?
11-deoxycortisol + H2O2 Reichstein's substance S Marasmius wettsteinii ? + H2O
-
 ?
11-deoxycortisol + H2O2 Reichstein's substance S Marasmius wettsteinii DSM 106021 ? + H2O
-
 ?
4-nitrobenzaldehyde + H2O2
-
 Cyclocybe aegerita 4-nitrobenzoic acid + H2O
-
 ?
4-nitrobenzaldehyde + H2O2
-
 Marasmius rotula 4-nitrobenzoic acid + H2O
-
 ?
4-nitrobenzaldehyde + H2O2
-
 Marasmius wettsteinii 4-nitrobenzoic acid + H2O
-
 ?
4-nitrobenzaldehyde + H2O2
-
 Marasmius wettsteinii DSM 106021 4-nitrobenzoic acid + H2O
-
 ?
cortisone + H2O2
-
 Marasmius rotula cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
cortisone + H2O2
-
 Marasmius wettsteinii cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
cortisone + H2O2
-
 Marasmius wettsteinii DSM 106021 cortisone 21-gem-diol + cortisone 21-oic acid + adrenosterone + H2O
-
 ?
cortisone 21-al + H2O2
-
 Marasmius rotula cortisone 21-oic acid + H2O
-
 ?
cortisone 21-al + H2O2
-
 Marasmius wettsteinii cortisone 21-oic acid + H2O
-
 ?
cortisone 21-al + H2O2
-
 Marasmius wettsteinii DSM 106021 cortisone 21-oic acid + H2O
-
 ?
additional information the enzyme shows no activity with cortisone and negligible oxidation of prednisone and 11-deoxycortisol Cyclocybe aegerita ?
-
-
prednisone + H2O2
-
 Marasmius rotula ? + H2O
-
 ?
prednisone + H2O2
-
 Marasmius wettsteinii ? + H2O
-
 ?
veratryl alcohol + H2O2
-
 Marasmius rotula veratraldehyde + H2O
-
 ?
veratryl alcohol + H2O2
-
 Marasmius wettsteinii veratraldehyde + H2O
-
 ?
veratryl alcohol + H2O2
-
 Marasmius wettsteinii DSM 106021 veratraldehyde + H2O
-
 ?

Subunits

Subunits Comment Organism
homodimer 2 * 32500, SDS-PAGE Marasmius wettsteinii
homodimer 2 * 32000, SDS-PAGE Marasmius rotula
homodimer 2 * 46000, SDS-PAGE Cyclocybe aegerita

Synonyms

Synonyms Comment Organism
UPO
-
 Cyclocybe aegerita
UPO
-
 Marasmius rotula
UPO
-
 Marasmius wettsteinii

Turnover Number [1/s]

Turnover Number Minimum [1/s] Turnover Number Maximum [1/s] Substrate Comment Organism Structure
0.102
-
 cortisone at pH 5.5 and 23°C Marasmius wettsteinii
0.107
-
 cortisone at pH 5.5 and 23°C Marasmius rotula

Cofactor

Cofactor Comment Organism Structure
heme
-
 Cyclocybe aegerita
heme
-
 Marasmius rotula
heme
-
 Marasmius wettsteinii